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Selenium (7782-49-2)

Identification
Name:Selenium
Synonyms:C.I. 77805;Colloidal selenium;Elemental selenium;Gray selenium;Selen;Selenate;Selenium alloy;Selenium base;Selenium dust;Selenium elemental;Selenium, colloidal;Selenium, metallic;Vandex;
CAS:7782-49-2
EINECS: 231-957-4
Molecular Formula: Se
Molecular Weight: 78.96
InChI: InChI=1/Se
Molecular Structure: (Se) C.I. 77805;Colloidal selenium;Elemental selenium;Gray selenium;Selen;Selenate;Selenium alloy;Seleniu...
Properties
Transport:UN 3077
Density:4.81
Stability:Stable. Incompatible with strong acids, strong oxidizing agents and most common metals. Combustible.
Water Solubility:insoluble
Solubility:H2O: soluble
Appearance:DARK RED-BROWN TO BLUISH-BLACK AMORPHOUS SOLID OR RED TRANSPARENT CRYSTALS OR METALLIC GREY TO BLACK CRYSTALS.
Specification:

The Selenium , with the cas number 7782-49-2, a chemical element with the atomic number 34, and, also exists in many non-conductive forms: a black glass-like allotrope, as well as several red crystalline forms built of eight-membered ring molecules. It is found in economic quantities in sulfide ores and occurs in several different forms, the most stable of which is a dense purplish-gray semi-metal form that is structurally a trigonal polymer chain. Its natural sources include certain selenium-rich soils, and selenium that has been bioconcentrated by certain plants. Native selenium is a rare mineral, which does not usually form good crystals, but when it does they are steep rhombohedrons or tiny acicular (hair-like) crystals. Selenium has five naturally occurring isotopes are stable: 74Se, 76Se, 77Se, 78Se, and 80Se. It is toxic in large doses, but Selenium is an essential micronutrient for animals. Dietary selenium comes from nuts, cereals, meat, fish, and eggs.

It belongs to the following product categories:(1)Inorganics; (2)Pure ElementsChemical Synthesis; (3)SeleniumMetal and Ceramic Science; (4)Catalysis and Inorganic Chemistry; (5)Electronic Chemicals; (6)Micro/Nanoelectronics; (7)Metal and Ceramic Science; (8)Metals; (9)Selenium and so on. It seems to be dark grey to dark red powder or crystals. It is quite stable but combustible, incompatible with strong acids, strong oxidizing agents and most common metals.

Uses of Selenium: Although it is toxic in large doses, selenium is an essential micronutrient for animals. Besides, Selenium also plays a role in the functioning of the thyroid gland and in every cell that utilizes thyroid hormone, by participating as a cofactor for the three known thyroid hormone deiodinases, which activate and then deactivate various thyroid hormones and their metabolites. One study, which was known as the NPC, was conducted to test the effect of selenium supplementation on the recurrence of skin cancers on selenium-deficient men. And, several studies have suggested a possible link between cancer and selenium deficiency. Also, some research has indicated a geographical link between regions of selenium-deficient soils and peak incidences of HIV/AIDS infection. It has been showed that selenium intake is positively correlated with the risk of developing type 2 diabetes.

When you are using this chemical, please be cautious about it as the following: It is quite irritating to eyes and skin. In addition, it is toxic by inhalation and if swallowed and bring danger of cumulative effects. When using, do not eat or drink or smoke. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap-suds. Most important of all, it may cause long-term adverse effects in the aquatic environment. Hence, you would better avoid release to the environment refering to special instructions / safety data sheets.

You can still convert the following datas into molecular structure :
(1).SMILES: [Se-2]
(2).InChI:InChI=1/Se/q-2

Toxic information of Selenium can be showed as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rabbit LDLo intravenous 2500ug/kg (2.5mg/kg) ? Journal of Obstetrics and Gynaecology of the British Empire. Vol. 35, Pg. 693, 1928.
rat LCLo inhalation 33mg/m3/8H (33mg/m3) BLOOD: HEMORRHAGE

LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA

LUNGS, THORAX, OR RESPIRATION: CHANGES IN LUNG WEIGHT
AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 4, Pg. 458, 1951.
rat LD50 intravenous 6mg/kg (6mg/kg) ? AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 4, Pg. 458, 1951.
rat LD50 oral 6700mg/kg (6700mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Toxicology and Applied Pharmacology. Vol. 20, Pg. 89, 1971.

Report:

IARC Cancer Review: Group 3 IMEMDT ?? IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.:?) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Selenium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Packinggroup: III
Color: SELENIUM EXISTS IN SEVERAL ALLOTROPIC FORMS. 3 ARE GENERALLY RECOGNIZED ... SELENIUM CAN BE PREPD WITH EITHER AMORPHOUS OR CRYSTALLINE STRUCTURE. ... AMORPHOUS IS EITHER RED, IN POWDER FORM OR BLACK, IN VITREOUS FORM. CRYSTALLINE MONOCLINIC PRISM IS DEEP RED; CRYSTALLINE HEXAGONAL FORM, THE MOST STABLE VARIETY, IS A METALLIC GRAY.
Safety Data
Hazard Symbols T:Toxic