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4-Nitro-o-phenylenediamine (99-56-9)

Identification
Name:4-Nitro-o-phenylenediamine
Synonyms:3,4-Diaminonitrobenzene; Nitroophenylenediamine; 2-Amino-4-nitro aniline; 4-nitrobenzene-1,2-diamine
CAS:99-56-9
EINECS: 202-766-3
Molecular Formula: C6H7N3O2
Molecular Weight: 153.14
InChI: InChI=1/C6H7N3O2/c7-5-2-1-4(9(10)11)3-6(5)8/h1-3H,7-8H2
Molecular Structure: (C6H7N3O2) 3,4-Diaminonitrobenzene; Nitroophenylenediamine; 2-Amino-4-nitro aniline; 4-nitrobenzene-1,2-diamine
Properties
Transport:UN 2811
Density:1.446g/cm3
Stability:Stable. Incompatible with strong acids, strong reducing agents, strong oxidizing agents, acid chlorides, acid anhydrides.
Refractive index:1.708
Solubility:1.2 g/L (20 ºC)
Appearance:Orange-red powder
Specification:

  1,2-Benzenediamine,4-nitro- , its cas register number is 99-56-9. It also can be called  1,2-Benzenediamine, 4-nitro- ; 1,2-Diamino-4-nitrobenzene ; 2-Amino-4-nitroaniline ; 3,4-Diaminonitrobenzene ; 4-13-00-00075 (Beilstein Handbook Reference) ; 4-Nitro-1,2-benzenediamine ; 4-Nitro-o-phenylene-diamine ; 4-Nitro-para-phenylenediamine ; 4-Nitrophenylenediamine ; Nitro-o-phenylenediamine ; p-Nitro-o-phenylenediamine .

Report:

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 16 (1978),p. 63.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-180 ,1979. . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Packinggroup: II
HS Code: 29215119
Storage Temperature: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Color: Dark red needles from dilute alcohol
Usage:1,2-Diamino-4-nitrobenzene is used in semi-permanent & permanent hair coloring products. It produces brown, red & blond shades on hair. It has typically been used in medium-brown & medium-red dye formulations. It has also been used in bleach-toner formulations for reddish-blond shades.
Safety Data
Hazard Symbols Xn:Harmful