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Triethylenediamine

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[Flash Point]

62.2
[Autoignition]

350
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
[Upper exp. limit]

9.2
[Lower exp. limit]

1.2
[Fire Potential]

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
[Ingestion]

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
[Ingestion]

The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
[Inhalation]

May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Inhalation of dust may cause respiratory tract irritation.
[Skin]

Causes severe skin irritation and possible burns.
[Eyes]

Causes severe eye irritation and possible burns.
[Hazards]

Contact with metals may evolve flammable hydrogen gas.
[EC Risk Phrase]

R 22 34
[EC Safety Phrase]

S 26 36/37/39 45
[UN (DOT)]

3263
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Poison Class]

3
[Appearance]

White crystals with a sharp, ammonia-like odor. Sublimes readily at room temperature, hygroscopic.
[Solubility in water]

460 g/L
[Boiling Point]

174
[Vapor Pressure]

1.2 (25 C)
[Density]

1.14 g/cm3 (20 C)
[pKa/pKb]

5.30 (pKb)
[Partition Coefficient]

-.85
[Heat Of Vaporization]

41.0 kJ/mol
[Usage]

Catalyst in making urethane foams.
[Saturation Concentration]

600 ppm at 20 C
[Product Name]

1,4-Diazabicyclo[2.2.2]octane
[Synonyms]

1,4-Diazabicyclo[2.2.2]octane
Dabco
Quinuclidine
[CAS]

"CASEN_280-57-9.htm">280-57-9
[Formula]

C6H12N2
[Molecular Weight]

112.18
[EINECS]

205-999-9
[RTECS]

HM0354200
[RTECS Class]

Primary Irritant
[Merck]

12,9801
[Beilstein/Gmelin]

103618
[Beilstein Reference]

5-23-03-00487
[EC Class]

harmful, irritant, dangerous for the environment
[Small spills/leaks]

Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
[Disposal Code]

3
[Stability]

Stable under normal temperatures and pressures.
[Incompatibilities]

Strong oxidizing agents, strong acids. Forms an explosive complex with hydrogen peroxide. Mixtures with carbon auto-ignite at 230C. Very exothermic reaction with cellulose nitrate.
[Decomposition]

Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

3263
[Hazard Class]

8
[Packing Group]

I; II; III
[HS Code]

2933 59 20