| [Flash Point] -16 | |
| [Autoignition] 240 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. May polymerize explosively when involved in a fire. Containers may explode when heated. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out. | |
| [Upper exp. limit] 13.8 | |
| [Lower exp. limit] 1.1 | |
| [Fire Potential] HIGHLY FLAMMABLE. | |
| [Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. | |
| [Skin] Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
| [Storage] Keep away from heat, sparks, and flame. Keep away from heat and flame. Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area. | |
| [Handling] Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. | |
| [Inhalation] Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Vapors may cause dizziness or suffocation. | |
| [Skin] Causes skin irritation. | |
| [Eyes] Causes eye irritation. | |
| [Ingestion] Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. | |
| [Hazards] Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. | |
| [EC Risk Phrase] R 11 36/38 | |
| [EC Safety Phrase] S 16 26 33 36 | |
| [UN (DOT)] 2376 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Exposure Effects] The toxological properties of this substance have not been fully investigated. | |
| [Poison Class] 3 | |
| [Appearance] A clear colorless liquid with an ethereal odor. | |
| [Solubility in water] Soluble | |
| [Melting Point] -70 | |
| [Boiling Point] 86 | |
| [Vapor Pressure] 74 (25 C) | |
| [Density] 0.923 g/cm3 (20 C) | |
| [Partition Coefficient] 1.06 | |
| [Heat Of Vaporization] 31.3 kJ/mol | |
| [Heat Of Combustion] -2955 kJ/mol | |
| [Usage] This cyclic ether is used to protect alcohols in organic synthesis. | |
| [Vapor Density] 2.9 | |
| [Refractive Index] 1.4402 (19 C) | |
| [Product Name] 3,4-Dihydro-2H-pyran | |
| [Synonyms] 3,4-Dihydro-2H-pyran Dihydropyran | |
| [CAS] "CASEN_110-87-2.htm">110-87-2 | |
| [Formula] C5H8O | |
| [Molecular Weight] 84.12 | |
| [EINECS] 203-810-4 | |
| [RTECS] UP7700000 | |
| [Beilstein/Gmelin] 103493 | |
| [Beilstein Reference] 5-17-01-00181 | |
| [EC Class] highly flammable, irritant, harmful | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Scoop up with a nonsparking tool, then place into a suitable container for disposal. Cover with an activated carbon adsorbent and place into a closed container for disposal. Remove all sources of ignition. Provide ventilation. | |
| [Disposal Code] 1 | |
| [Incompatibilities] Oxidizing agents, strong acids, and alcohols. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Decomposition] Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 2376 | |
| [Hazard Class] 3 | |
| [Packing Group] II | |
| [HS Code] 2932 99 95 |
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