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Tetramethyl-1,3-diaminopropane

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[Flash Point]

31
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam.
[Fire Potential]

Flammable/combustible material. May be ignited by heat, sparks or flames.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Get medical aid immediately. Remove from exposure to fresh air immediately. Do not use mouth-to-mouth respiration if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
[Skin]

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.
[Storage]

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Keep containers tightly closed.
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Use and store under nitrogen. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapors.
[Inhalation]

Exposure produces central nervous system depression. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Harmful if inhaled.
[Skin]

Harmful if absorbed through the skin. May cause severe irritation and possible burns. Substance is readily absorbed through the skin. May cause cyanosis of the extremities.
[Eyes]

Contact with eyes may cause severe irritation, and possible eye burns. May cause chemical conjunctivitis and corneal damage.
[Ingestion]

Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression.
[Hazards]

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
[EC Risk Phrase]

R 10 20/22 24 34
[EC Safety Phrase]

S 26 28 36/37/39 45
[UN (DOT)]

2924
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
[Exposure Effects]

Effects may be delayed.
[Poison Class]

3
[Appearance]

Clear, colorless liquid.
[Solubility in water]

Very soluble
[Boiling Point]

145
[Density]

0.7837 g/cm3 (19 C)
[pKa/pKb]

4.12 (pKb)
[Vapor Density]

4.49
[Refractive Index]

1.4215 (18.7 C)
[Product Name]

N,N,N',N'-Tetramethyl-1,3-propanediamine
[Synonyms]

2,6-Dimethyl-2,6-diazaheptane
Bis[(dimethylamino)methyl]methane
N,N,N',N'-Tetramethyl-1,3-propanediamine
TMPDA
[CAS]

"CASEN_110-95-2.htm">110-95-2
[Formula]

C7H18N2
[Molecular Weight]

130.22999999999999
[EINECS]

203-818-8
[RTECS]

TX8400000
[RTECS Class]

Other
[Beilstein/Gmelin]

1734176
[Beilstein Reference]

4-04-00-01259
[Small spills/leaks]

Clean up spills immediately, using the appropriate protective equipment. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. A vapor suppressing foam may be used to reduce vapors.
[Incompatibilities]

Acid chlorides, acids, acid anhydrides, strong oxidizing agents, carbon dioxide.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Nitrogen oxides, carbon monoxide, carbon dioxide.
[Combustion Products]

Fire will produce irritating, corrosive and/or toxic gases.
[UN Number]

2924
[Hazard Class]

3
[Packing Group]

I; II; III