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Dichloroacetic acid methyl ester

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[Flash Point]

70
[Autoignition]

484
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. Extinguishing media: Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
[Fire Potential]

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
[Ingestion]

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration.
[Skin]

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
[Eyes]

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
[Storage]

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
[Handling]

Wash thoroughly after handling. Use only in a well ventilated area. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
[Ingestion]

May cause severe and permanent damage to the digestive tract. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Causes gastrointestinal tract burns.
[Inhalation]

Causes respiratory tract irritation. Causes chemical burns to the respiratory tract. Vapors may cause dizziness or suffocation.
[Skin]

Causes second and third degree burns on short contact, especially if skin is moist or wet.
[Eyes]

Causes eye burns.
[Hazards]

Vapors form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff.
[EC Risk Phrase]

R 36/37/38
[UN (DOT)]

2299
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Poison Class]

4
[Appearance]

A colorless liquid with an ethereal odor.
[Solubility in water]

Reacts
[Melting Point]

-52
[Boiling Point]

143
[Vapor Pressure]

35 (20 C)
[Density]

1.3774 g/cm3 (20 C)
[Usage]

Used to make other chemicals.
[Vapor Density]

4.93
[Refractive Index]

1.4429 (20 C)
[Product Name]

Dichloroacetic acid methyl ester
[Synonyms]

1,1-Dichloro-2-methoxy-2-oxoethane
Acetic acid, dichloro-, methyl ester
Dichloroacetic acid methyl ester
Methyl 2,2-dichloroacetate
[CAS]

"CASEN_116-54-1.htm">116-54-1
[Formula]

C3H4Cl2O2
[Molecular Weight]

142.97
[EINECS]

204-146-8
[RTECS]

AG6625000
[RTECS Class]

Other
[Beilstein/Gmelin]

1747542
[Beilstein Reference]

4-02-00-00501
[EC Class]

irritant
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation. Do not get water inside containers.
[Disposal Code]

2
[Incompatibilities]

Oxidizing agents, reducing agents, acids, bases.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
[Combustion Products]

Produces toxic fumes of phosgene and HCl.
[UN Number]

2299
[Hazard Class]

6.1
[Packing Group]

III
[HS Code]

2915 40 00