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2,2'-Dithiosalicylic acid

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[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Inhalation]

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
[Skin]

May cause skin irritation.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

May cause eye irritation.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Storage]

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator (approx 4 C).
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
[Ingestion]

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
[Ingestion]

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
[Inhalation]

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
[Skin]

May cause skin irritation. The toxicological properties of this material have not been fully investigated.
[Eyes]

May cause eye irritation. The toxicological properties of this material have not been fully investigated.
[EC Risk Phrase]

R 36/37/38
[EC Safety Phrase]

S 26 36
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Respirators]

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
[Appearance]

Off white to light yellow powder.
[Appearance]

Off-white to tan powder.
[Solubility in water]

Soluble
[Melting Point]

254 - 256
[Melting Point]

283 - 286
[Boiling Point]

502
[pKa/pKb]

3.02 (pKa)
[Partition Coefficient]

4.01
[Usage]

Biosynthetic intermediate.
[Product Name]

2,2'-Dithiodibenzoic acid
[Synonyms]

2-(2-Carboxyphenyl)disulfanylbenzoic acid
2,2'-Dithiobis(benzoic acid)
2,2'-Dithiodibenzoic acid
2-Amino-3-(5-methoxy-1H-indol-3-yl)propanoic acid
Bis(2-carboxyphenyl) disulfide
Diphenyl disulfide-2,2'-dicarboxylic acid
DL-Tryptophan, 5-methoxy-
NSC 405662
[CAS]

"CASEN_119-80-2.htm">119-80-2
[CAS]

"CASEN_28052-84-8.htm">28052-84-8
[Formula]

C12H14N2O3
[Formula]

C14H10O4S2
[Molecular Weight]

234.25
[Molecular Weight]

306.36
[EINECS]

204-352-8
[EINECS]

248-800-0
[RTECS]

DG9660000
[RTECS Class]

Other
[Merck]

12,3440
[Beilstein/Gmelin]

2221810
[Beilstein/Gmelin]

26781
[Beilstein Reference]

4-10-00-00279
[Beilstein Reference]

5-22-14-00279
[Small spills/leaks]

Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.
[Small spills/leaks]

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
[Disposal Code]

4
[Incompatibilities]

Oxidizing agents.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Carbon monoxide, oxides of sulfur, carbon dioxide.
[Decomposition]

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
[HS Code]

2930 90 70