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4-Chloro-3-nitrobenzotrifluoride

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[Flash Point]

101
[Autoignition]

>450
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
[Fire Potential]

May burn but does not ignite readily.
[Ingestion]

Get medical aid. Wash mouth out with water.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

May cause skin irritation.
[Skin]

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

May cause eye irritation.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Storage]

Store in a cool, dry place. Store in a tightly closed container.
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
[Handling]

Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
[Ingestion]

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
[Inhalation]

Harmful if inhaled. May cause cyanosis, characterized by bluish-colored skin.
[Skin]

Harmful if absorbed through the skin.
[Eyes]

May cause eye irritation.
[Ingestion]

Harmful if swallowed. May cause nausea and vomiting. May cause unconsciousness.
[Hazards]

Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
[EC Risk Phrase]

R 20/21/22 36/38
[EC Risk Phrase]

R 36/37/38
[EC Safety Phrase]

S 26 36
[EC Safety Phrase]

S 26 36/37/39
[UN (DOT)]

2307
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Personal Protection]

Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Exposure Effects]

The toxological properties of this substance have not been fully investigated.
[Exposure limit(s)]

2.5 mg/m3 as F (ACGIH)
[Appearance]

A colorless to dark-colored liquid.
[Appearance]

Light yellow tinted powder.
[Solubility in water]

660 mg/L
[Melting Point]

-3
[Melting Point]

127.5
[Boiling Point]

154 - 158 (0.2 - 0.3 torr)
[Boiling Point]

223
[Vapor Pressure]

.04
[Density]

1.391 g/cm3
[Density]

1.5421 g/cm3 (21 C)
[Usage]

Chemical intermediate for herbicides, eg, fluorodifen.
[Refractive Index]

1.4905 (20 C)
[Product Name]

3-Nitro-4-chlorobenzotrifluoride
[Synonyms]

1,4-Diformylpiperazine
1,4-Piperazine dialdehyde
1,4-Piperazinedicarboxaldehyde
1-Chloro-2-nitro-4-(trifluoromethyl)benzene
2-Chloro-5-(trifluoromethyl)nitrobenzene
3-Nitro-4-chloro-1-(trifluoromethyl)benzene
4-Chloro-3-nitro-alpha,alpha,alpha-trifluorotoluene
4-Trifluoromethyl-2-nitrochlorobenzene
Benzene, 1-chloro-2-nitro-4-(trifluoromethyl)
[CAS]

"CASEN_121-17-5.htm">121-17-5
[CAS]

"CASEN_4164-39-0.htm">4164-39-0
[Formula]

C6H10N2O2
[Formula]

C7H3ClF3NO2
[Molecular Weight]

225.55
[Molecular Weight]

142.15
[EINECS]

204-451-6
[EINECS]

224-011-7
[RTECS]

XS9140000
[RTECS Class]

Mutagen; Primary Irritant
[Beilstein/Gmelin]

523986
[Beilstein/Gmelin]

121175
[Beilstein Reference]

4-05-00-00857
[Beilstein Reference]

5-23-01-00044
[EC Class]

harmful, irritant
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
[Small spills/leaks]

Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.
[Stability]

No data.
[Stability]

Stable under normal temperatures and pressures.
[Incompatibilities]

Strong bases, strong oxidizing agents.
[Incompatibilities]

Strong oxidizing agents.
[Decomposition]

Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide.
[Decomposition]

Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2307
[Hazard Class]

6.1
[Packing Group]

II
[HS Code]

2904 90 85