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2'-Bromoacetophenone

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[Flash Point]

87
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Fire Potential]

Combustible material: may burn but does not ignite readily.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation.
[Inhalation]

May cause respiratory tract irritation. Can produce delayed pulmonary edema.
[Skin]

Causes skin irritation.
[Eyes]

Causes eye irritation. May cause chemical conjunctivitis.
[Ingestion]

May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
[Hazards]

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
[EC Risk Phrase]

R 36/38
[EC Safety Phrase]

S 26 36
[UN (DOT)]

2810
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
[Exposure Effects]

Effects may be delayed.
[Appearance]

Clear pale yellow liquid.
[Solubility in water]

Insoluble
[Melting Point]

0
[Boiling Point]

249
[Vapor Pressure]

0.024 (25 C)
[Density]

1.471 g/cm3 (30 C)
[Partition Coefficient]

2.02
[Heat Of Vaporization]

48.6 kJ/mol
[Vapor Density]

6.86
[Refractive Index]

1.57 (20 C)
[Product Name]

1-(2-Bromophenyl)ethanone
[Synonyms]

Ethanone, 1-(2-bromophenyl)-
o-Bromoacetophenone
[CAS]

"CASEN_2142-69-0.htm">2142-69-0
[Formula]

C8H7BrO
[Molecular Weight]

199.05
[EINECS]

218-398-1
[Beilstein/Gmelin]

1931534
[Beilstein Reference]

4-07-00-00646
[EC Class]

irritant
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
[Stability]

Stable under normal temperatures and pressures.
[Incompatibilities]

Strong oxidizing agents, strong bases.
[Decomposition]

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2810
[Hazard Class]

6.1
[Packing Group]

I; II; III
[HS Code]

2914 70 90