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Dichloromethylphenylsilane

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[Flash Point]

72
[Autoignition]

> 400
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Substance will react with water (some violently) releasing flammable, toxic, or corrosive gases and runoff. Extinguishing media: For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Do NOT get water inside containers. Do NOT use straight streams of water. For small fires, use carbon dioxide, dry chemical, dry sand, or alcohol-resistant foam. Most foams will react with the material and release corrosive/toxic gases.
[Upper exp. limit]

8.6
[Lower exp. limit]

.2
[Fire Potential]

Combustible material: may burn but does not ignite readily.
[Ingestion]

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
[Skin]

Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
[Eyes]

Get medical aid. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
[Storage]

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
[Handling]

Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
[Inhalation]

May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated. Aspiration may lead to pulmonary edema. May cause systemic effects. Inhalation at high concentrations may cause CNS depression and asphixiation.
[Skin]

Causes skin burns. May cause irritation and dermatitis. May cause cyanosis of the extremities. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
[Eyes]

Causes eye burns. May cause chemical conjunctivitis and corneal damage.
[Ingestion]

May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May cause systemic effects.
[Hazards]

When heated to decomposition, it emits toxic fumes of chlorine-containing compounds. Flammable/combustible material; may be ignited by heat, sparks, or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Reacts strongly with oxidizing materials.
[EC Risk Phrase]

R 34 37
[EC Safety Phrase]

S 26 36/37/39 45
[UN (DOT)]

2437
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Exposure Effects]

Effects may be delayed.
[Appearance]

A colorless liquid.
[Solubility in water]

Decomposes
[Boiling Point]

205
[Vapor Pressure]

1
[Density]

1.1767 g/cm3
[Usage]

Chemical intermediate for silicone fluids, resins, & elastomers.
[Vapor Density]

6.59
[Refractive Index]

1.5188
[Product Name]

Dichloromethylphenylsilane
[Synonyms]

Dichloro(methyl)(Phenyl)silane
Dichloromethylphenylsilane
Phenylmethyldichlorosilane
[CAS]

"CASEN_149-74-6.htm">149-74-6
[Formula]

C7H8Cl2Si
[Molecular Weight]

191.13
[EINECS]

205-746-2
[RTECS]

VV3530000
[RTECS Class]

Organometallic
[Beilstein/Gmelin]

970975
[Beilstein Reference]

4-16-00-01517
[EC Class]

corrosive
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
[Disposal Code]

8
[Incompatibilities]

Ammonia, strong oxidizing agents.
[Stability]

Stable at room temperature in closed containers under normal storage and handling conditions.
[Decomposition]

Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
[Combustion Products]

During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
[UN Number]

2437
[Hazard Class]

8
[Packing Group]

II
[HS Code]

2931 00 95