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Phenyl chlorothionocarbonate

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[Flash Point]

87
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
[Fire Potential]

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
[Ingestion]

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
[Skin]

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Discard contaminated clothing in a manner which limits further exposure. Destroy contaminated shoes.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
[Storage]

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator (approx 4 C).
[Handling]

Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
[Ingestion]

Causes severe digestive tract burns.
[Inhalation]

May cause severe respiratory tract irritation and possible burns.
[Skin]

Causes skin burns.
[Eyes]

Causes eye burns.
[Hazards]

Contact with metals may evolve flammable hydrogen gas.
[EC Risk Phrase]

R 34
[EC Safety Phrase]

S 26 36/37/39 45
[UN (DOT)]

1760
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

Clear yellow liquid.
[Solubility in water]

Insoluble
[Melting Point]

0
[Boiling Point]

221
[Vapor Pressure]

0.17 (25 C)
[Density]

1.283 g/cm3 (15 C)
[Partition Coefficient]

3.26
[Heat Of Vaporization]

43.8 kJ/mol
[Vapor Density]

5.95
[Refractive Index]

1.58 (20 C)
[Product Name]

Phenyl chlorothionocarbonate
[Synonyms]

Carbonochloridothioic acid, O-phenyl ester
Formic acid, chlorothio-, O-phenyl ester
O-Phenyl carbonochloridothioate
O-Phenyl chlorothionoformate
Phenoxythiocarbonyl chloride
Phenyl thionochloroformate
[CAS]

"CASEN_1005-56-7.htm">1005-56-7
[Formula]

C7H5ClOS
[Molecular Weight]

172.63
[EINECS]

213-736-4
[Beilstein/Gmelin]

774830
[Beilstein Reference]

3-06-00-00609
[EC Class]

corrosive
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.
[Disposal Code]

11
[Stability]

Stable under normal temperatures and pressures. May decompose on exposure to moist air or water.
[Incompatibilities]

Strong oxidizing agents.
[Decomposition]

Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen fluoride.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

1760
[Hazard Class]

8
[Packing Group]

I; II; III
[HS Code]

2930 90 70