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4-Dimethylaminopyridine

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[Flash Point]

124
[Autoignition]

420
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use water spray, dry chemical, or carbon dioxide.
[Fire Potential]

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
[Ingestion]

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
[Skin]

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Discard contaminated clothing in a manner which limits further exposure.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.
[Storage]

Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.
[Ingestion]

Harmful if swallowed. May cause severe and permanent damage to the digestive tract.
[Inhalation]

May cause severe irritation of the respiratory tract with possible burns.
[Skin]

May be fatal if absorbed through the skin. Causes skin burns.
[Eyes]

Causes eye burns.
[Hazards]

Contact with metals may evolve flammable hydrogen gas.
[EC Risk Phrase]

R 23/24/25 36/37/38
[EC Safety Phrase]

S 26 28 36/37/39 45
[UN (DOT)]

2811
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

Off white to brown solid.
[Solubility in water]

Very soluble
[Melting Point]

109 - 111
[Boiling Point]

195
[Vapor Pressure]

0.43 (25 C)
[Density]

0.41 g/cm3 (20 C)
[pKa/pKb]

4.48 (pKb)
[Partition Coefficient]

1.34
[Heat Of Vaporization]

43.1 kJ/mol
[Product Name]

4-Dimethylaminopyridine
[Synonyms]

4-Dimethylaminopyridine
DMAP
gamma-(Dimethylamino)pyridine
N,N-Dimethylpyridin-4-amine
Pyridine, 4-(dimethylamino)-
[CAS]

"CASEN_1122-58-3.htm">1122-58-3
[Formula]

C7H10N2
[Molecular Weight]

122.17
[EINECS]

214-353-5
[RTECS]

US9230000
[RTECS Class]

Other
[Beilstein/Gmelin]

110354
[Beilstein Reference]

5-22-09-00112
[EC Class]

toxic, irritant
[Small spills/leaks]

Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.
[Disposal Code]

3
[Stability]

Stable under normal temperatures and pressures.
[Incompatibilities]

Strong oxidizing agents.
[Decomposition]

Nitrogen oxides, carbon monoxide, carbon dioxide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2811
[Hazard Class]

6.1
[Packing Group]

I; II; III
[HS Code]

2933 39 99