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Hexadecanethiol

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[Flash Point]

99
[Autoignition]

260
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide. Water may be ineffective. Use agent most appropriate to extinguish fire.
[Fire Potential]

Combustible material: may burn but does not ignite readily.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use only in a chemical fume hood.
[Ingestion]

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May cause nausea and vomiting.
[Inhalation]

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May cause nausea, dizziness, and headache.
[Skin]

May cause skin irritation.
[Eyes]

May cause eye irritation.
[Hazards]

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
[EC Safety Phrase]

S 24/25
[UN (DOT)]

2810
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
[Exposure limit(s)]

NIOSH REL: C 0.5 ppm (5.3 mg/m3) 15-minute
[Poison Class]

4
[Appearance]

Colorless liquid, strong odor.
[Solubility in water]

Insoluble
[Melting Point]

18 - 20
[Boiling Point]

335
[Vapor Pressure]

0.0002 (25 C)
[Density]

0.8556 g/cm3 (20 C)
[pKa/pKb]

10.57 (pKa)
[Partition Coefficient]

8.69
[Heat Of Vaporization]

55.5 kJ/mol
[Usage]

Used as a polymerization conditioner; intermediate in organic synthesis; used in tarnish-preventing agents.
[Vapor Density]

8.9
[Refractive Index]

1.4630 (20 C)
[Product Name]

Cetyl mercaptan
[Synonyms]

1-Mercaptohexadecane
Cetyl mercaptan
Hexadecane-1-thiol
Hexadecyl mercaptan
[CAS]

"CASEN_2917-26-2.htm">2917-26-2
[Formula]

C16H34S
[Molecular Weight]

258.51
[EINECS]

220-846-6
[Beilstein/Gmelin]

1748495
[Beilstein Reference]

4-01-00-01881
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
[Disposal Code]

6
[Stability]

Stable under normal temperatures and pressures.
[Incompatibilities]

Strong acids, strong bases, oxidizing agents, reducing agents, alkali metals.
[Decomposition]

Carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, hydrogen sulfide.
[Combustion Products]

During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
[UN Number]

2810
[Hazard Class]

6.1
[Packing Group]

I; II; III
[HS Code]

2930 90 70