| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam. | |
| [Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | |
| [Skin] Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
| [Storage] Store in a cool, dry place. Store in a tightly closed container. Storage under a nitrogen blanket has been recommended. | |
| [Handling] Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. | |
| [Ingestion] May cause irritation of the digestive tract. | |
| [Inhalation] May cause respiratory tract irritation. | |
| [Skin] May cause skin irritation. | |
| [Eyes] May cause eye irritation. | |
| [EC Risk Phrase] R 36/37/38 | |
| [EC Safety Phrase] S 26 36 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Appearance] White to off-white powder. | |
| [Melting Point] 140 - 142 | |
| [Usage] Reagent for conversion of primary and secondary alcohols to chlorides and bromides: oxide byproduct filtrable. | |
| [Product Name] Bis(1,2-diphenylphosphino)ethane | |
| [Synonyms] 2-Di(phenyl)phosphanylethyl-di(phenyl)phosphane Diphos DPPE Phosphine, 1,2-ethanediylbis[diphenyl- | |
| [CAS] "CASEN_1663-45-2.htm">1663-45-2 | |
| [Formula] C26H24P2 | |
| [Molecular Weight] 398.43 | |
| [EINECS] 216-769-2 | |
| [Beilstein/Gmelin] 761261 | |
| [Beilstein Reference] 4-16-00-00958 | |
| [EC Class] irritant | |
| [Small spills/leaks] Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Incompatibilities] Strong oxidizing agents. | |
| [Decomposition] Phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide. | |
| [HS Code] 2931 00 95 |
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