| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER! | |
| [Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
| [Ingestion] If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. | |
| [Skin] Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
| [Storage] Store in a tightly closed container. Keep under a nitrogen blanket. Store in a cool, dry, well-ventilated area away from incompatible substances. | |
| [Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Do not allow water to get into the container because of violent reaction. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. | |
| [Inhalation] May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. | |
| [Skin] May cause severe skin irritation with possible burns, especially if skin is wet or moist. | |
| [Eyes] Lachrymator. Causes eye irritation and possible burns. | |
| [Ingestion] May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [UN (DOT)] 1760 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Exposure Effects] May cause liver and kidney damage. | |
| [Appearance] Colorless, fuming liquid | |
| [Solubility in water] Hydrolyzes | |
| [Melting Point] -52 | |
| [Boiling Point] 82 | |
| [Density] 1.84 g/cm3 | |
| [Usage] Intermediate in the production of purified germanium metal. In fiber optic production. | |
| [Product Name] Germanium chloride | |
| [Synonyms] Germanium tetrachloride Tetrachlorogermane | |
| [CAS] "CASEN_10038-98-9.htm">10038-98-9 | |
| [Formula] Cl4Ge | |
| [Molecular Weight] 214.4 | |
| [EINECS] 233-116-7 | |
| [RTECS] LY5225000 | |
| [RTECS Class] Mutagen; Primary Irritant | |
| [Merck] 12,4418 | |
| [Beilstein/Gmelin] 184751 (G) | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Provide ventilation. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Incompatibilities] Strong oxidizing agents. | |
| [Decomposition] Hydrogen chloride. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1760 | |
| [Hazard Class] 8 | |
| [Packing Group] I; II; III |
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