| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | |
| [Ingestion] Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
| [Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture. | |
| [Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. | |
| [Inhalation] May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. | |
| [Skin] May cause skin irritation. | |
| [Eyes] May cause eye irritation. | |
| [Ingestion] May cause irritation of the digestive tract. May be harmful if swallowed. | |
| [Hazards] During a fire, irritating and highly toxic gasesmay be generated by thermal decomposition or combustion. | |
| [EC Risk Phrase] R 22 34 43 | |
| [EC Safety Phrase] S 26 36/37/39 45 | |
| [UN (DOT)] 3260 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Reproductive effects have been reported in animals. | |
| [Poison Class] 3 | |
| [Appearance] Red monoclinic crystals or black crystalline powder. | |
| [Density] 5.38 g/cm3 (20 C) | |
| [Usage] Catalysts. | |
| [Product Name] Rhodium (III) chloride | |
| [Synonyms] Rhodium trichloride | |
| [CAS] "CASEN_10049-07-7.htm">10049-07-7 | |
| [Formula] Cl3H8O4Rh | |
| [Molecular Weight] 209.26 | |
| [EINECS] 233-165-4 | |
| [RTECS] VI9275000 | |
| [RTECS Class] Tumorigen; Mutagen; Reproductive Effector | |
| [Merck] 12,8355 | |
| [Beilstein/Gmelin] 35366 (G) | |
| [Small spills/leaks] Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. | |
| [Incompatibilities] Moisture, strong oxidizing agents. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Decomposition] Irritating and toxic fumes and gases, oxides of chlorine, rhodium/rhodium oxides. | |
| [UN Number] 3260 |
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