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Ethyl acetohydroxamate

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[Flash Point]

77
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
[Ingestion]

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
[Inhalation]

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
[Skin]

May cause skin irritation. The toxicological properties of this material have not been fully investigated.
[Eyes]

May cause eye irritation. The toxicological properties of this material have not been fully investigated.
[EC Risk Phrase]

R 10 36/38
[EC Safety Phrase]

S 26 36
[UN (DOT)]

1993
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

White solid.
[Solubility in water]

Soluble
[Melting Point]

27 - 28
[Boiling Point]

165
[Vapor Pressure]

0.7 (25 C)
[pKa/pKb]

12.03 (pKa)
[Partition Coefficient]

.89
[Heat Of Vaporization]

46.7 kJ/mol
[Refractive Index]

1.43 (20 C)
[Product Name]

Ethyl N-hydroxyacetimidate
[Synonyms]

Acetohydroximic acid, ethyl ester
Ethanimidic acid, N-hydroxy-, ethyl ester
Ethyl acetate, oxime
Ethyl acetohydroxamate
Ethyl acetohydroximate
N-(1-Ethoxyethylidene)hydroxylamine
[CAS]

"CASEN_10576-12-2.htm">10576-12-2
[Formula]

C4H9NO2
[Molecular Weight]

103.12
[EINECS]

234-165-7
[Beilstein/Gmelin]

1700260
[Beilstein Reference]

2-02-00-00184
[Small spills/leaks]

Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Remove all sources of ignition. Provide ventilation.
[Stability]

Stable under normal temperatures and pressures.
[Incompatibilities]

Strong oxidizing agents, strong acids, strong bases, strong reducing agents.
[Decomposition]

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
[UN Number]

1993