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Magnesium phosphide

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[Fire Fighting]

Do not extinguish fire unless flow can be stopped. Do not use water. Use graphite, soda ash, powdered sodium chloride, or suitable dry powder.
[Ingestion]

Seek medical assistance.
[Inhalation]

Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.
[Skin]

Remove and isolate contaminated clothing and shoes. In case of contact with substance, wipe from skin immediately. Flush with running water for at least 20 minutes.
[Eyes]

Flush with running water for at least 20 minutes.
[Storage]

Protect from moist air - will react to produce highly toxic phosphine.
[Handling]

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
[Inhalation]

Highly toxic: contact with water produces toxic gas, may be fatal if inhaled. Inhalation or contact with vapors, substance, or decomposition products may cause severe injury or death.
[Skin]

See Inhalation.
[Eyes]

May cause burns.
[Hazards]

Produce flammable and toxic gases on contact with water. May ignite on contact with water or moist air. Some react vigorously or explosively on contact with water. May be ignited by heat, sparks or flames. May re-ignite after fire is extinguished. Some are transported in highly flammable liquids. Runoff may create fire or explosion hazard.
[UN (DOT)]

2011
[Personal Protection]

Wear appropriate chemical protective clothing.
[Respirators]

Wear positive pressure self-contained breathing apparatus.
[Exposure Effects]

The toxological properties of this substance have not been fully investigated.
[Poison Class]

1
[Appearance]

Green to yellow crystals
[Solubility in water]

Reacts
[Melting Point]

>750
[Density]

2.055 g/cm3 (25 C)
[Usage]

Insecticide.
[Product Name]

Magnesium phosphide
[Synonyms]

Fumi-Cel
Magtoxin
Trimagnesium diphosphide
[CAS]

"CASEN_12057-74-8.htm">12057-74-8
[Formula]

Mg3P2
[Molecular Weight]

134.87
[EINECS]

235-023-7
[RTECS]

OM4200000
[RTECS Class]

Other
[Beilstein/Gmelin]

169799 (G)
[EC Index Number]

015-005-00-3
[EC Class]

Highly flammable; Very toxic; Dangerous for the Environment
[Small spills/leaks]

Do not use water. Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Keep material dry.
[Stability]

No data.
[Incompatibilities]

React vigorously with most oxidants.
[Combustion Products]

Fire will produce irritating, corrosive and/or toxic gases.
[UN Number]

2011
[Hazard Class]

4.3
[Packing Group]

I