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3-Aminopyridine

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[Flash Point]

88
[Autoignition]

628
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
[Fire Potential]

Combustible material: may burn but does not ignite readily.
[Ingestion]

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
[Skin]

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Poison room locked.
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use only in a chemical fume hood.
[Ingestion]

May be fatal if swallowed. May cause irritation of the digestive tract. Poison by ingestion. May cause effects similar to those for inhalation exposure. An oral dose of 590 mg/kg of 4-aminopyridine in a man produced shortness of breath, nausea, vomiting, hallucinations and distorted perception. Affects the CNS to produce tremor, excitability and convulsions.
[Inhalation]

Causes respiratory tract irritation. May cause severe headaches, nausea, increased blood pressure, weakness, convulsions, and a stuporous state.
[Skin]

Causes skin irritation. May be fatal if absorbed through the skin. Substance is rapidly absorbed through the skin. Causes symptoms similar to those of inhalation. Causes redness and pain.
[Eyes]

Causes eye irritation. Causes redness and pain.
[Hazards]

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
[EC Risk Phrase]

R 23/24 28 33 36/37/38
[EC Safety Phrase]

S 23 26 28 36/37/39 45
[UN (DOT)]

2671
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

White to brown crystals.
[Solubility in water]

Soluble
[Melting Point]

60 - 63
[Boiling Point]

248
[Vapor Pressure]

0.02 (25 C)
[pKa/pKb]

7.82 (pKb)
[Partition Coefficient]

-.02
[Heat Of Vaporization]

48.8 kJ/mol
[Usage]

Insecticide.
[Vapor Density]

3.25
[Product Name]

3-Pyridinamine
[Synonyms]

3-Aminopyridine
[CAS]

"CASEN_462-08-8.htm">462-08-8
[Formula]

C5H6N2
[Molecular Weight]

94.12
[EINECS]

207-322-2
[RTECS]

US1650000
[RTECS Class]

Drug
[Merck]

13,472
[Beilstein/Gmelin]

8145294
[EC Class]

toxic, irritant
[Small spills/leaks]

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
[Disposal Code]

3
[Incompatibilities]

Oxidizing agents, strong acids, acid chlorides, acid anhydrides
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Nitrogen oxides, carbon monoxide, carbon dioxide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2671
[Hazard Class]

6.1
[Packing Group]

II
[HS Code]

2933 39 99