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Pentyl nitrite

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[Flash Point]

9
[Autoignition]

205
[Fire Fighting]

Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of water may spread fire. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbon dioxide.
[Ingestion]

DO NOT INDUCE VOMITING. Volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital.
[Inhalation]

IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
[Skin]

IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
[Eyes]

First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
[Storage]

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
[Handling]

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
[Ingestion]

See inhalation.
[Inhalation]

Inhalation or ingestion causes flushing of the face, pulsatile headache, disturbing tachycardia, cyanosis (methemoglobinemia), weakness, confusion, restlessness, faintness, and collapse. Contact with eyes or skin causes irritation.
[Skin]

See inhalation.
[Eyes]

See inhalation
[Hazards]

Toxic oxides of nitrogen are formed. Behavior in Fire: Containers may explode.
[EC Risk Phrase]

R 11 20/22
[EC Safety Phrase]

S 16 24 46
[UN (DOT)]

1113
[Personal Protection]

Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
[Respirators]

Use NIOSH/MSHA approved respirator appropriate for exposure of concern.
[Poison Class]

2
[Appearance]

A clear colorless to yellowish liquid with a fragrant, fruity odor and pungent aromatic taste.
[Solubility in water]

Insoluble
[Boiling Point]

104
[Vapor Pressure]

35 (25 C)
[Density]

0.8809 g/cm3 (19 C)
[Partition Coefficient]

2.64
[Heat Of Vaporization]

33.0 kJ/mol
[Heat Of Combustion]

-1945 kJ/mol
[Usage]

Used in medicine and to make other chemicals.
[Vapor Density]

4
[Refractive Index]

1.3871 (20 C)
[Product Name]

Pentyl nitrite
[Synonyms]

Amyl nitrite
itramyl
Nitrous acid, pentyl ester
Pentyl nitrite
[CAS]

"CASEN_463-04-7.htm">463-04-7
[Formula]

C5H11NO2
[Molecular Weight]

117.15
[EINECS]

207-332-7
[RTECS]

RA1140000
[RTECS Class]

Mutagen
[Beilstein/Gmelin]

1701241
[Beilstein Reference]

4-01-00-01644
[EC Index Number]

007-020-00-9
[EC Class]

Highly flammable; Harmful
[Small spills/leaks]

Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Use water spray to knock-down vapors. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder, or commercial sorbents. Water spill: Use natural barriers or oil spill control booms to limit spill travel. Remove trapped material with suction hoses.
[Incompatibilities]

If mixed with reducing agents, including hydrides, sulfides and nitrides,
[Stability]

No data.
[Combustion Products]

Toxic oxides of nitrogen are formed.
[UN Number]

1113
[HS Code]

2920 90 85