| [Flash Point] -2 | |
| [Fire Fighting] Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Use foam, dry chemical, or carbon dioxide. Cool all affected containers with flooding quantities of water. Do not use water on material itself. If large quantities of combustibles are involved, use water in flooding quantities as spray and fog. Use water spray to knock-down vapors. | |
| [Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. | |
| [Skin] Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. | |
| [Eyes] Get medical aid. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes). | |
| [Storage] Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator (approx 4 C). Do not store in metal containers. Keep containers tightly closed. Store protected from moisture. Store under an inert atmosphere. | |
| [Handling] Wash thoroughly after handling. Ground and bond containers when transferring material. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Do not ingest or inhale. Handle under an inert atmosphere. Store protected from air. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. | |
| [Ingestion] Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed. | |
| [Inhalation] Causes severe respiratory tract irritation with possible burns. | |
| [Skin] Causes severe skin irritation and possible burns. | |
| [Eyes] Causes severe eye irritation and possible burns. | |
| [Hazards] Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Contact with metals may evolve flammable hydrogen gas. | |
| [UN (DOT)] 2474 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. | |
| [Respirators] Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. | |
| [Appearance] A reddish liquid. | |
| [Solubility in water] Slightly soluble | |
| [Boiling Point] 73 | |
| [Vapor Pressure] 127 (25 C) | |
| [Density] 1.5085 g/cm3 (15 C) | |
| [Partition Coefficient] 2.07 | |
| [Heat Of Vaporization] 30.1 kJ/mol | |
| [Heat Of Combustion] -8000 kJ/mol | |
| [Usage] Organic synthesis. | |
| [Vapor Density] 4 | |
| [Refractive Index] 1.54424 | |
| [Product Name] Thiophosgene | |
| [Synonyms] Carbon chlorosulfide Carbonothioic dichloride Thiocarbonyl chloride | |
| [CAS] "CASEN_463-71-8.htm">463-71-8 | |
| [Formula] CCl2S | |
| [Molecular Weight] 114.97 | |
| [EINECS] 207-341-6 | |
| [RTECS] XN2450000 | |
| [RTECS Class] Primary Irritant | |
| [Beilstein/Gmelin] 1633495 | |
| [Beilstein Reference] 4-03-00-00281 | |
| [EC Index Number] 607-201-00-8 | |
| [EC Class] Toxic; Harmful; Irritant | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. | |
| [Incompatibilities] Acids - bases - alcohols - amines - metals - moist air or water. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Decomposition] Hydrogen chloride, phosgene, oxides of sulfur, irritating and toxic fumes and gases. | |
| [Combustion Products] Toxic phosgene, hydrogen chloride, and sulfur dioxide may be generated in a fire. | |
| [UN Number] 2474 | |
| [Hazard Class] 6.1 | |
| [Packing Group] II |
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