| [Flash Point] 102 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out. | |
| [Fire Potential] Combustible material: may burn but does not ignite readily. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Inhalation] Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
| [Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | |
| [Handling] Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse. | |
| [Inhalation] Causes respiratory tract irritation. May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea, and death. May cause cardiac abnormalities. Can produce delayed pulmonary edema. | |
| [Skin] Causes skin irritation. | |
| [Eyes] Causes eye irritation. May cause chemical conjunctivitis. | |
| [Ingestion] May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause methemoglobinemia, cyanosis, convulsions, and death. May cause central nervous system depression. May cause cardiac abnormalities. | |
| [Hazards] When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. | |
| [EC Risk Phrase] R 20/21/22 33 | |
| [EC Safety Phrase] S 28 36/37 | |
| [UN (DOT)] 2810 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Exposure Effects] May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. Effects may be delayed. | |
| [Appearance] Clear brown liquid. | |
| [Solubility in water] Insoluble | |
| [Melting Point] 26 | |
| [Boiling Point] 240 | |
| [Vapor Pressure] 0.04 (25 C) | |
| [Density] 1.498 g/cm3 (20 C) | |
| [pKa/pKb] 11.03 (pKb) | |
| [Partition Coefficient] 2.65 | |
| [Heat Of Vaporization] 47.7 kJ/mol | |
| [Vapor Density] 6.4 | |
| [Refractive Index] 1.5999 (20 C) | |
| [Product Name] 4-Amino-3-bromotoluene | |
| [Synonyms] 2-Bromo-4-methylbenzenamine 2-Bromo-4-methylphenylamine 2-Bromo-4-toluidine 3-Bromo-4-aminotoluene 4-Amino-3-bromotoluene o-Bromo-p-toluidine | |
| [CAS] "CASEN_583-68-6.htm">583-68-6 | |
| [Formula] C7H8BrN | |
| [Molecular Weight] 186.06 | |
| [EINECS] 209-515-7 | |
| [RTECS] XU4300000 | |
| [RTECS Class] Mutagen | |
| [Beilstein/Gmelin] 1931711 | |
| [Beilstein Reference] 4-12-00-01992 | |
| [EC Class] irritant | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation. | |
| [Incompatibilities] Oxidizing agents. | |
| [Stability] Stable at room temperature in closed containers under normal storage and handling conditions. | |
| [Decomposition] Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide, nitrogen. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 2810 | |
| [Hazard Class] 6.1 | |
| [Packing Group] I; II; III | |
| [HS Code] 2921 43 00 |
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