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Ethyl methanesulfonate

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[Flash Point]

100
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Use agent most appropriate to extinguish fire.
[Fire Potential]

This chemical is combustible.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
[Handling]

Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
[Inhalation]

May cause respiratory tract irritation.
[Skin]

May cause skin irritation.
[Eyes]

May cause eye irritation.
[Ingestion]

May cause irritation of the digestive tract.
[EC Risk Phrase]

R 45 46 20/21/22
[EC Safety Phrase]

S 53 45
[UN (DOT)]

2810
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Exposure Effects]

May cause cancer according to animal studies.
[Exposure limit(s)]

OSHA: Possible Select carcinogen
[Poison Class]

1*
[Appearance]

Clear colorless liquid.
[Solubility in water]

Soluble
[Boiling Point]

213
[Vapor Pressure]

.34
[Density]

1.2079 g/cm3 (20 C)
[Partition Coefficient]

.09
[Usage]

Biochemical research.
[Refractive Index]

1.4194 (15 C)
[Product Name]

Ethyl methanesulfonate
[Synonyms]

Ethyl mesylate
Ethyl methanesulfonate
Ethylmesilate
Half-myleran
Methanesulfonic acid, ethyl ester
O-Ethyl methylsulfonate
[CAS]

"CASEN_62-50-0.htm">62-50-0
[Formula]

C3H8O3S
[Molecular Weight]

124.16
[EINECS]

200-536-7
[RTECS]

PB2100000
[RTECS Class]

Tumorigen; Drug; Mutagen; Reproductive Effector
[Merck]

13,3859
[Beilstein/Gmelin]

773969
[Beilstein Reference]

4-04-00-00012
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
[Stability]

Stable under normal temperatures and pressures.
[Incompatibilities]

Strong oxidizing agents, strong bases.
[Decomposition]

Carbon monoxide, oxides of sulfur, carbon dioxide.
[UN Number]

2810