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Methyl phenylacetate

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[Flash Point]

91
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
[Ingestion]

May cause digestive tract disturbances.
[Inhalation]

May cause respiratory tract irritation.
[Skin]

Causes skin irritation.
[Eyes]

May cause eye irritation.
[EC Safety Phrase]

S 24/25
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

Clearly, slightly yellow liquid. Astrong odor similar to honey.
[Solubility in water]

Insoluble
[Melting Point]

49 - 50
[Boiling Point]

218
[Vapor Pressure]

0.13 (25 C)
[Density]

1.0808 g/cm3 (0 C)
[Partition Coefficient]

1.97
[Heat Of Vaporization]

45.4 kJ/mol
[Usage]

Used in the flavor industry and in perfumes to impart honey scents.
[Vapor Density]

5.18
[Refractive Index]

1.5075 (20 C)
[Product Name]

Methyl phenylacetate
[Synonyms]

Methyl phenylacetate
[CAS]

"CASEN_101-41-7.htm">101-41-7
[Formula]

C9H10O2
[Molecular Weight]

150.18
[EINECS]

202-940-9
[RTECS]

AJ3175000
[RTECS Class]

Primary Irritant
[Merck]

12,7422
[Beilstein/Gmelin]

878795
[Beilstein Reference]

4-09-00-01617
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Wash area with soap and water. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.
[Incompatibilities]

Oxidizing agents
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Carbon monoxide, carbon dioxide, acrid smoke and fumes.
[HS Code]

2916 35 00