| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use extinguishing media most appropriate for the surrounding fire. Do NOT get water inside containers. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.  | |
| [Ingestion] If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.  | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.  | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.  | |
| [Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.  | |
| [Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from acids. Store protected from moisture.  | |
| [Handling] Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use only in a chemical fume hood. Wash clothing before reuse. Keep from contact with moist air and steam.  | |
| [Inhalation] Causes respiratory tract irritation.  | |
| [Skin] Causes skin irritation.  | |
| [Eyes] Causes eye irritation.  | |
| [Ingestion] May cause gastrointestinal irritation with nausea, vomiting and diarrhea.  | |
| [Personal Protection] Eyes: Wear chemical goggles. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron. Wear appropriate protective clothing to prevent skin exposure.  | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.  | |
| [Exposure Effects] Chronic exposure to fluoride compounds may cause systemic toxicity.  | |
| [Appearance] white monoclinic crystals  | |
| [Density] 4.43 g/cm3  | |
| [Usage] A component of zblan fluoride glass.  | |
| [Product Name] Zirconium tetrafluoride  | |
| [Synonyms] Tetrafluorozirconium Zirconium tetrafluoride  | |
| [CAS] "CASEN_7783-64-4.htm">7783-64-4  | |
| [Formula] F4Zr  | |
| [Molecular Weight] 167.21  | |
| [EINECS] 232-018-1  | |
| [RTECS] ZH7875000  | |
| [RTECS Class] Other  | |
| [Merck] 12,10308  | |
| [Beilstein/Gmelin] 26063 (G)  | |
| [Small spills/leaks] Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.  | |
| [Stability] Stable under normal temperatures and pressures.  | |
| [Incompatibilities] Strong oxidizing agents, strong acids.  | |
| [Decomposition] Hydrogen fluoride.  |