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Methyl cyanoacetate

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[Flash Point]

110
[Autoignition]

478
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Upper exp. limit]

13
[Fire Potential]

Combustible material: may burn but does not ignite readily.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
[Ingestion]

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
[Inhalation]

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
[Skin]

May cause skin irritation. The toxicological properties of this material have not been fully investigated.
[Eyes]

May cause eye irritation. The toxicological properties of this material have not been fully investigated.
[Hazards]

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
[EC Risk Phrase]

R 36
[EC Safety Phrase]

S 26 36
[UN (DOT)]

2810
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Poison Class]

4
[Appearance]

Light yellow liquid.
[Solubility in water]

54 g/L
[Melting Point]

-22.5
[Boiling Point]

207
[Vapor Pressure]

0.98 (20 C)
[Density]

1.1225 g/cm3 (25C)
[Vapor Density]

3.4
[Refractive Index]

1.4176 (20 C)
[Product Name]

Methyl cyanoacetate
[Synonyms]

(Methoxycarbonyl)acetonitrile
Acetic acid, cyano-, methyl ester
Cyanoacetic acid methyl ester
Methyl 2-cyanoacetate
Methyl cyanoethanoate
[CAS]

"CASEN_105-34-0.htm">105-34-0
[Formula]

C4H5NO2
[Molecular Weight]

99.09
[EINECS]

203-288-8
[RTECS]

AG4375000
[RTECS Class]

Other
[Beilstein/Gmelin]

6120280
[Beilstein Reference]

3-03-00-00451
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
[Disposal Code]

9
[Incompatibilities]

Oxidizing agents.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2810
[Hazard Class]

6.1
[Packing Group]

I; II; III
[HS Code]

2926 90 95