| [Flash Point] 163 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Combustible material; may burn but does not ignite readily. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | |
| [Fire Potential] Nonflammable. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
| [Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | |
| [Handling] Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse. | |
| [Inhalation] Causes respiratory tract irritation. May cause liver and kidney damage. Can produce delayed pulmonary edema. | |
| [Skin] Causes skin irritation. May be harmful if absorbed through the skin. | |
| [Eyes] Causes eye irritation. May cause chemical conjunctivitis. | |
| [Ingestion] Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver and kidney damage. Human fatalities have been reported from acute poisoning. | |
| [Hazards] Containers may explode when heated. | |
| [EC Risk Phrase] R 22 37 41 43 52/53 | |
| [EC Safety Phrase] S 24/25 26 36/37/39 46 61 | |
| [UN (DOT)] 2765 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] May cause liver and kidney damage. Effects may be delayed. | |
| [Exposure limit(s)] TLV: ppm; 10 mg/m3 (as TWA) (ACGIH 1993-1994). OSHA PEL: TWA 10 mg/m3 NIOSH REL: TWA 10 mg/m3 NIOSH IDLH: 100 mg/m3 | |
| [Poison Class] 3 | |
| [Appearance] White to yellow, crystalline powder, odorless when pure, may have a slight phenolic odor due to impurities. | |
| [Solubility in water] Very soluble | |
| [Melting Point] 137 - 139 | |
| [Boiling Point] 346 | |
| [Vapor Pressure] 2E-5 (25 C) | |
| [Density] 1.563 g/cm3 (20 C) | |
| [pKa/pKb] 2.98 (pKa) | |
| [Partition Coefficient] 2.81 | |
| [Heat Of Vaporization] 62.2 kJ/mol | |
| [Heat Of Combustion] -3915 kJ/mol | |
| [Usage] It is registered in the usa as a herbicide for control of broadleaf plants & as a plant-growth regulator. | |
| [Vapor Density] 7.63 | |
| [Saturation Concentration] 526 ppm (0.05%) at 160 C (calculated) | |
| [Odor threshold] 3.13 mg/kg | |
| [Product Name] 2,4-D LV6 | |
| [Synonyms] 2-(2,4-Dichlorophenoxy)acetic acid 2,4-D Fernimine Hedonal Vergemaster | |
| [CAS] "CASEN_94-75-7.htm">94-75-7 | |
| [Formula] C8H6Cl2O3 | |
| [Molecular Weight] 221.04 | |
| [EINECS] 202-361-1 | |
| [RTECS] AG6825000 | |
| [RTECS Class] Agricultural Chemical and Pesticide; Tumorigen; Mutagen; Reproductive Effector; Human Data; Primary Irritant | |
| [Merck] 13,2825 | |
| [Beilstein/Gmelin] 1214242 | |
| [Beilstein Reference] 4-06-00-00908 | |
| [EC Index Number] 607-039-00-8 | |
| [EC Class] Harmful; Irritant; Sensitising; Dangerous for the Environment | |
| [Small spills/leaks] Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. | |
| [Stability] Stable at room temperature in closed containers under normal storage and handling conditions. | |
| [Incompatibilities] Strong oxidizing agents, strong acids, strong bases. | |
| [Decomposition] Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. | |
| [Combustion Products] Toxic and irritating hydrogen chloride or phosgene gases may form. | |
| [UN Number] 2765 | |
| [Hazard Class] 3.2 | |
| [Packing Group] III | |
| [HS Code] 2918 90 90 |
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