| [Flash Point] 48 | |
| [Autoignition] > 600 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. | |
| [Upper exp. limit] 12.6 | |
| [Lower exp. limit] 1 | |
| [Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
| [Fire Potential] Slight risk when exposed to heat or flame. | |
| [Ingestion] Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Ingestion] If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
| [Inhalation] May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. | |
| [Skin] May cause skin irritation. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Eyes] May cause eye irritation. | |
| [Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
| [Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
| [Storage] Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. | |
| [Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | |
| [Handling] Wash thoroughly after handling. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. | |
| [Handling] Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. | |
| [Ingestion] May cause digestive tract disturbances. | |
| [Ingestion] May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. | |
| [Inhalation] Causes severe respiratory tract irritation. Vapors may cause dizziness or suffocation. | |
| [Skin] Causes severe skin irritation. | |
| [Eyes] Causes severe eye irritation. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [Hazards] Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. | |
| [EC Risk Phrase] R 20 51/53 | |
| [EC Safety Phrase] S 24/25 61 | |
| [UN (DOT)] 2238 | |
| [UN (DOT)] 2811 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure limit(s)] NIOSH REL: TWA 50 ppm (250 mg/m3) ST 75 ppm (375 mg/m3) | |
| [Poison Class] 3 (Strong toxins) | |
| [Appearance] Colorless liquid. | |
| [Appearance] White powder. | |
| [Solubility in water] 90 mg/L | |
| [Melting Point] 161 | |
| [Melting Point] -36 | |
| [Boiling Point] 159 | |
| [Vapor Pressure] 3 | |
| [Density] 1.0825 g/cm3 | |
| [Partition Coefficient] 3.42 | |
| [Heat Of Vaporization] 43.10 kJ/mol | |
| [Heat Of Combustion] -3747 kJ/mol | |
| [Usage] Solvent, dyestuff intermediate, in organic syntheses. | |
| [Vapor Density] 4.38 | |
| [Saturation Concentration] 4.7 x 10(3) ppm (0.47%) at 25 C (calculated) | |
| [Refractive Index] 1.5352 | |
| [Product Name] 1-Chloro-2-methylbenzene | |
| [Synonyms] 1-Chloro-2-Methylbenzene 2,4-Dicyano-3-methylpentanediamide 2-Chloro-1-Methylbenzene alpha,gamma-Dicyano-beta-methyl-glutaramide o-Chlorotoluene | |
| [CAS] "CASEN_95-49-8.htm">95-49-8 | |
| [CAS] "CASEN_5447-66-5.htm">5447-66-5 | |
| [Formula] C7H7Cl | |
| [Formula] C8H10N4O2 | |
| [Molecular Weight] 126.59 | |
| [Molecular Weight] 194.19 | |
| [EINECS] 202-424-3 | |
| [EINECS] 226-665-9 | |
| [RTECS] MA3000000 | |
| [RTECS] XS9000000 | |
| [RTECS Class] Other | |
| [RTECS Class] Primary Irritant | |
| [Merck] 13,2190 | |
| [Beilstein/Gmelin] 1712402 | |
| [Beilstein/Gmelin] 1904175 | |
| [Beilstein Reference] 3-02-00-02080 | |
| [Beilstein Reference] 4-05-00-00805 | |
| [EC Index Number] 602-040-00-X | |
| [EC Class] Harmful; Dangerous for the Environment | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. A vapor suppressing foam may be used to reduce vapors. | |
| [Small spills/leaks] Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. | |
| [Disposal Code] 2 | |
| [Incompatibilities] Oxidizing agents, reducing agents, acids, alkalis. | |
| [Stability] Stable at room temperature in closed containers under normal storage and handling conditions. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Incompatibilities] Strong acids, strong bases, strong oxidizing agents, strong reducing agents. | |
| [Decomposition] Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide. | |
| [Decomposition] Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, chlorine. | |
| [Combustion Products] May contain toxic chloride fumes. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 2238 | |
| [UN Number] 2811 | |
| [Hazard Class] 3 | |
| [Hazard Class] 6.1 | |
| [Packing Group] I; II; III | |
| [Packing Group] III | |
| [HS Code] 2903 69 90 |
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