| [Flash Point] 252 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | |
| [Fire Potential] This chemical is combustible. | |
| [Ingestion] If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | |
| [Skin] Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
| [Storage] Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | |
| [Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. | |
| [Inhalation] Causes irritation of the mucous membrane and upper respiratory tract. | |
| [Skin] Causes skin irritation. May cause allergic sensitization in certain individuals. | |
| [Eyes] Causes eye irritation. | |
| [Ingestion] May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed. Rapidly absorbed when ingested and disseminated throughout the body. Strongly accumulted by thyroid tissue and slowly released. | |
| [EC Risk Phrase] R 61 22 | |
| [EC Safety Phrase] S 53 45 | |
| [UN (DOT)] 2811 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Possible cancer hazard based on tests with laboratory animals. Laboratory experiments have resulted in mutagenic effects. May be rapidly transferred across the placenta and cause adverse fetal effects. | |
| [Exposure limit(s)] NIOSH REL: Ca Use encapsulated form. See Appendix A NIOSH IDLH: Potential occupational carcinogen | |
| [Poison Class] 1* | |
| [Appearance] White to pale green crystals or an off-white solid. Odorless when pure, but technical product may have an amine odor. | |
| [Solubility in water] 20 g/L | |
| [Melting Point] 196 - 199 | |
| [Vapor Pressure] 16 | |
| [Density] 1.417 g/cm3 | |
| [Partition Coefficient] -.66 | |
| [Usage] It was found that etu was present in 28 different ethylenebisdithiocarbamate commercial products. | |
| [Product Name] 1,3-Ethylenethiourea | |
| [Synonyms] 2-Imidazolidinethione 2-Mercaptoimidazoline ETU Imidazolidine-2-thione | |
| [CAS] "CASEN_96-45-7.htm">96-45-7 | |
| [Formula] C3H6N2S | |
| [Molecular Weight] 102.16 | |
| [EINECS] 202-506-9 | |
| [RTECS] NI9625000 | |
| [RTECS Class] Agricultural Chemical and Pesticide; Tumorigen; Mutagen; Reproductive Effector; Primary Irritant | |
| [Merck] 13,3837 | |
| [Beilstein/Gmelin] 106275 | |
| [Beilstein Reference] 5-24-01-00165 | |
| [EC Index Number] 613-039-00-9 | |
| [EC Class] Toxic for reproduction Category 2; Harmful | |
| [Small spills/leaks] Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. | |
| [Disposal Code] 9 | |
| [Incompatibilities] Acrolein, strong oxidizing agents. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Decomposition] Nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, nitrogen. | |
| [UN Number] 2811 | |
| [HS Code] 2933 29 90 |
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