| [Flash Point] 79 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. | |
| [Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
| [Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
| [Inhalation] Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. | |
| [Skin] Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. | |
| [Eyes] Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes). | |
| [Storage] Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. | |
| [Handling] Wash thoroughly after handling. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Use only in a chemical fume hood. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. | |
| [Inhalation] Causes chemical burns to the respiratory tract. Inhalation of bromides may cause irritation of the upper respiratory tract and lung tissue. | |
| [Skin] Causes skin burns. | |
| [Eyes] Causes eye burns. Lachrymator. | |
| [Ingestion] May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [EC Risk Phrase] R 34 36 | |
| [EC Safety Phrase] S 26 36/37/39 45 | |
| [UN (DOT)] 1760 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Chronic ingestion may cause bromism characterized by disturbances of the central nervous system, skin and digestive tract. | |
| [Appearance] Colorless liquid. | |
| [Solubility in water] Insoluble | |
| [Boiling Point] 59 - 61 (3.5 torr) | |
| [Density] 1.61 g/cm3 | |
| [Vapor Density] 7.14 | |
| [Refractive Index] 1.53 (20 C) | |
| [Product Name] 3,4-Difluorobenzyl bromide | |
| [Synonyms] 4-(Bromomethyl)-1,2-difluorobenzene 4-Bromomethyl-1,2-difluorobenzene a-Bromo-3,4-difluorotoluene | |
| [CAS] "CASEN_85118-01-0.htm">85118-01-0 | |
| [Formula] C7H5BrF2 | |
| [Molecular Weight] 207.01 | |
| [EINECS] 285-653-1 | |
| [Beilstein/Gmelin] 742578 | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. | |
| [Stability] Stable at room temperature in closed containers under normal storage and handling conditions. | |
| [Incompatibilities] Strong oxidizing agents, strong bases. | |
| [Decomposition] Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride, hydrogen bromide. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1760 | |
| [Hazard Class] 8 | |
| [Packing Group] I; II; III |
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