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4-Nitrobenzyl bromide

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[Flash Point]

138
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustion generates toxic fumes. Extinguishing media: Do NOT use water directly on fire. Use dry chemical or carbon dioxide.
[Fire Potential]

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
[Ingestion]

The toxicological properties of this substance have not been fully investigated.
[Inhalation]

The toxicological properties of this substance have not been fully investigated.
[Skin]

No information regarding skin irritation and other potential effects was found.
[Eyes]

No information regarding eye irritation and other potential effects was found.
[Hazards]

Contact with metals may evolve flammable hydrogen gas.
[EC Risk Phrase]

R 34 36
[EC Safety Phrase]

S 26 36/37/39 45
[UN (DOT)]

2811
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

Beige crystals.
[Solubility in water]

Insoluble
[Melting Point]

94 - 96
[Boiling Point]

304
[Vapor Pressure]

0.0016 (25 C)
[Partition Coefficient]

2.65
[Heat Of Vaporization]

52.3 kJ/mol
[Product Name]

a-Brom-4-nitrotoluol
[Synonyms]

4-(Bromomethyl)nitrobenzene
4-Nitrobenzyl bromide
Benzene, 1-(bromomethyl)-4-nitro-
p-(Bromomethyl)nitrobenzene
p-Nitrobenzyl bromide
[CAS]

"CASEN_100-11-8.htm">100-11-8
[Formula]

C7H6BrNO2
[Molecular Weight]

216.04
[EINECS]

202-820-6
[RTECS]

XS7967000
[RTECS Class]

Mutagen
[Beilstein/Gmelin]

742796
[Beilstein Reference]

4-05-00-00861
[EC Class]

irritant, sensitizing
[Small spills/leaks]

Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions.
[Disposal Code]

3
[Incompatibilities]

Oxidizing agents.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide, nitrogen.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2811
[Hazard Class]

6.1
[Packing Group]

I; II; III
[HS Code]

2904 90 85