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4-Nitrobenzyl chloride

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[Flash Point]

130
[Fire Fighting]

Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Wear self-contained (positive pressure if available) breathing apparatus and full protective clothing.This material may burn but does not ignite readily. Small fires: dry chemical, carbon dioxide, water spray or foam. Large fires: Water spray, fog or foam. Move container from fire area if you can do it without risk.
[Fire Potential]

Combustible Liquid.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
[Ingestion]

Causes irritation.
[Inhalation]

Causes irritation.
[Skin]

Causes irritation.
[Eyes]

Causes irritation.
[Hazards]

Incompatible with sodium hydroxide.
[EC Risk Phrase]

R 20/21/22 34
[EC Safety Phrase]

S 26 36/37/39 45
[UN (DOT)]

2433
[Personal Protection]

Wear protective gloves and clothing and safety goggles.
[Respirators]

Not available.
[Solubility in water]

Insoluble
[Melting Point]

68 - 70
[Boiling Point]

293
[Vapor Pressure]

.0032
[Density]

1.5647 g/cm3 (20 C)
[Partition Coefficient]

2.22
[Heat Of Vaporization]

51.1 kJ/mol
[Product Name]

a-Chloro-4-nitrotoluene
[Synonyms]

1-(Chloromethyl)-4-nitrobenzene
4-Nitrophenylmethyl chloride
a-Chloro-p-nitrotoluene
p-(Chloromethyl)nitrobenzene
[CAS]

"CASEN_100-14-1.htm">100-14-1
[Formula]

C7H6ClNO2
[Molecular Weight]

171.59
[EINECS]

202-822-7
[RTECS]

XS9093000
[RTECS Class]

Mutagen
[Beilstein/Gmelin]

387187
[Beilstein Reference]

4-05-00-00856
[Small spills/leaks]

Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. If water pollution occurs, notify appropriate authorities. Do not touch spilled material; stop leak if you can do so without risk. Small spills: absorb with sand or other noncombustible absorbent material and place into containers for later disposal. Small dry spills: with clean shovel, place material into clean, dry container and cover; move containers from spill area. Large spills: dike far ahead of spill for alter disposal.
[Incompatibilities]

Incompatible with sodium hydroxide If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation.
[Stability]

Stable at room temperature in closed containers under normal storage and handling conditions.
[Combustion Products]

During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
[UN Number]

2433